Semiotic Index
A sign operates as an index when there is a concrete, tangible relationship between the signifier and the signified, as in:
Smoke→Fire
Fingerprint→Identity
Analogue groove in phonograph record→Voice/Other Sound Source
Some naturally occurring semiotic indices are natural binary oppositions, as well:
Reduced pupil opening→fear/anger/dislike vs. Dilated pupil opening→attraction/pleasure